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Desulfurization performance of iron-manganese-based sorbent for hot coal gas

Xiurong REN, Weiren BAO, Fan LI, Liping CHANG, Kechang XIE

《化学科学与工程前沿（英文）》 2010年第4卷第4期页码 429-434 doi: 10.1007/s11705-010-0504-y

摘要： A series of iron-manganese-based sorbents were prepared by co-precipitation and physical mixing method, and used for H S removal from hot coal gas. The sulfidation tests were carried out in a fixed-bed reactor with space velocity of 2000 h (STP). The results show that the suitable addition of manganese oxide in iron-based sorbent can decrease H S and COS concentration in exit before breakthrough due to its simultaneous reaction capability with H S and COS. Fe O and MnO are the initial active components in iron-manganese-based sorbent, and FeO and Fe are active components formed by reduction during sulfidation. The crystal phases of iron affect obviously their desulfurization capacity. The reducibility of sorbent changes with the content of MnO in sorbent. S7F3M and S3F7M have bigger sulfur capacities (32.68 and 32.30 gS/100 g total active component), while S5F5M has smaller sulfur capacity (21.92 gS/100 g total active component). S7F3M sorbent has stable sulfidation performance in three sulfidation-regeneration cycles and no apparent structure degradation. The sulfidation performance of iron- manganese-based sorbent is also related with its specific surface area and pore volume.

关键词： iron-manganese-based sorbent sulfidation performance regeneration hot coal gas

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Sulfidation/regeneration multicycle testing of nickel-modified ZnFe

Wei LI, Jinju GUO, Jiejie HUANG, Jiaotao ZHAO

《化学科学与工程前沿（英文）》 2010年第4卷第4期页码 435-440 doi: 10.1007/s11705-010-0506-9

摘要： A commercial metal oxide sorbent for the desulphurization of coal-derived gas requires high desulphurization reactivity, mechanical strength, ability to regenerate, and stability to endure many sulfidation-regeneration cycles. In this paper, the sulfur capacity and multiple cycles of a nickel-modified ZnFe O sorbent prepared by the sol-gel auto-combustion method were measured in a fixed-bed reactor at middle temperature of 300°C (sulfidation temperature) and 500°C (regeneration temperature). Also, the BET surface area, pore volume, average pore diameter and X-ray diffraction (XRD) patterns of the sorbent through multicycles were studied. Multicycle runs indicate that the sulfidation reactivity decreases slightly during the second cycle and keeps steady in the following cycles. The results indicate that the nickel-modified ZnFe O keeps high reactivity and structural stability in the multicycle testing of sulfidation/regeneration.

关键词： hot gas desulphurization nickel-modified ZnFe₂O₄ sulfidation/regeneration

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Remediation of arsenic contaminated soil by sulfidated zero-valent iron

《环境科学与工程前沿（英文）》 2021年第15卷第5期 doi: 10.1007/s11783-020-1377-z

摘要：

• Sulfidation significantly enhanced As(V) immobilization in soil by zerovalent iron.

关键词： Soil As(V) Sulfidation Zero-valent iron Magnetic separation

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A review on research and development of iron-based sorbents for removal of hydrogen sulfide from hot coal gases

Jianglong YU, Liping CHANG, Fan LI, Kechang XIE

《化学科学与工程前沿（英文）》 2010年第4卷第4期页码 529-535 doi: 10.1007/s11705-010-0519-4

摘要： In poly-generation and integrated gasification-combined cycle (IGCC) systems for clean energy conversion, it is essential to remove impurities such as sulfur species from hot coal gases prior to entering the subsequent units. This paper provides a comprehensive review on previous studies on high temperature removal of hydrogen sulfide from high temperature coal gases using iron-based sorbents. A two-step desulphurization process for hot coal gas cleanup is highlighted, which is integrated with direct production of elemental sulfur during regeneration of iron-based sorbents in the primary desulphurization step. Different kinetic modeling approaches for sulfidation and regeneration were compared. Limited research on activated carbon supported sorbents was also briefly summarized.

关键词： hot coal gas cleanup iron-based sorbents sulfidation regeneration sulphur recovery

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Performance-based and performance-driven architectural design and optimization

Xing SHI

《结构与土木工程前沿（英文）》 2010年第4卷第4期页码 512-518 doi: 10.1007/s11709-010-0090-6

摘要： As the architecture, engineering, and construction (AEC) industry is marching into the sustainable and low-carbon era, the performance of architecture has drawn more attention than ever. Simulation technology has made quantified analysis of architectural performance possible and, therefore, directly enables architects and engineers to incorporate performance analysis into the design work flow. It is argued that performance-based and performance-driven architectural designs differ in that the latter involves computer-aided optimization technique so that the performance can be used as the criteria to truly “drive” the design. The paper starts with a brief introduction of performance issues in architectural design, followed by a review of the evolution of performance-based architectural design. The concept of performance-driven architectural design is presented, and some design projects and research work are reviewed. The driving engine, i.e., optimization technique, and its application in architectural design is discussed. Challenges to making performance-driven design a common practice are explained, and a schematic of integrated performance-based/driven architectural design software is proposed.

关键词： performance optimization architectural design simulation sustainability

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Flexural and longitudinal shear performance of precast lightweight steel–ultra-high performance concrete

《结构与土木工程前沿（英文）》 2023年第17卷第5期页码 704-721 doi: 10.1007/s11709-023-0941-6

摘要： In this study, the flexural and longitudinal shear performances of two types of precast lightweight steel–ultra-high performance concrete (UHPC) composite beams are investigated, where a cluster UHPC slab (CUS) and a normal UHPC slab (NUS) are connected to a steel beam using headed studs through discontinuous shear pockets and full-length shear pockets, respectively. Results show that the longitudinal shear force of the CUS is greater than that of the NUS, whereas the interfacial slip of the former is smaller. Owing to its better integrity, the CUS exhibits greater flexural stiffness and a higher ultimate bearing capacity than the NUS. To further optimize the design parameters of the CUS, a parametric study is conducted to investigate their effects on the flexural and longitudinal shear performances. The square shear pocket is shown to be more applicable for the CUS, as the optimal spacing between two shear pockets is 650 mm. Moreover, a design method for transverse reinforcement is proposed; the transverse reinforcement is used to withstand the splitting force caused by studs in the shear pocket and prevent the UHPC slab from cracking. According to calculation results, the transverse reinforcement can be canceled when the compressive strength of UHPC is 150 MPa and the volume fraction of steel fiber exceeds 2.0%.

关键词： precast steel–UHPC composite beam flexural performance longitudinal shear performance parametric study transverse reinforcement ratio

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Experimental research on cyclone performance at high temperature

LI Wenqi, CHEN Jianyi

《机械工程前沿（英文）》 2007年第2卷第3期页码 310-317 doi: 10.1007/s11465-007-0055-1

摘要： To predict the influence of operating temperatures on cyclone performance, an experimental investigation was conducted on particle separation in a reverse flow, tangential volute-inlet cyclone separator with a diameter of 300 mm and with air heated up to 973 K. The test powder silica has a mass median diameter of 10 um, while inlet velocity range was 12-36 m/s. Both the separation efficiency and pressure drop of the cyclone were measured as a function of the inlet velocity and operating temperature. At the same inlet velocity, both the separation efficiency and pressure drop decrease with increasing temperature. In addition, optimum inlet velocity, at which the cyclone has its highest separation efficiency, tends to increase with a rise in temperature. An analysis on our own data and published results has shown that the fractional efficiency of a cyclone is a definite function of dimensionless numbers such as the Stokes number, the Reynolds number, the Froude number, dimensionless cyclone inlet area, and dimensionless outlet diameter. A nondimensional experimental correlation of the cyclone performance, including the influence of temperature, was obtained on the basis of our own previous work. The prediction of the influence of temperature on separation efficiencies and pressure drops is in fairly good agreement with experimental results.

关键词： diameter definite function nondimensional experimental cyclone performance influence

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Comparison of indices for stiffness performance evaluation

Giuseppe CARBONE, Marco CECCARELLI,

《机械工程前沿（英文）》 2010年第5卷第3期页码 270-278 doi: 10.1007/s11465-010-0023-z

摘要： This paper addresses the problem of a numerical evaluation of the stiffness performance for multibody robotic systems. An overview is presented with basic formulation concerning indices that are proposed in literature. New indices are also outlined. Stiffness indices are computed and compared for a case study. Results are used for comparing the effectiveness of the stiffness indices. The main goal is to propose a performance index describing synthetically the elastostatic response of a multibody robotic system and also for design purposes.

关键词： robotics stiffness performance indices

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Performance of steel bridge deck pavement structure with ultra high performance concrete based on resin

《结构与土木工程前沿（英文）》 2021年第15卷第4期页码 895-904 doi: 10.1007/s11709-021-0759-z

摘要： This research investigated a pavement system on steel bridge decks that use epoxy resin (EP) bonded ultra-high performance concrete (UHPC). Through FEM analysis and static and dynamic bending fatigue tests of the composite structure, the influences of the interface of the pavement layer, reinforcement, and different paving materials on the structural performance were compared and analyzed. The results show that the resin bonded UHPC pavement structure can reduce the weld strain in the steel plate by about 32% and the relative deflection between ribs by about 52% under standard axial load conditions compared to traditional pavements. The EP bonding layer can nearly double the drawing strength of the pavement interface from 1.3 MPa, and improve the bending resistance of the UHPC structure on steel bridge decks by about 50%; the bending resistance of reinforced UHPC structures is twice that of unreinforced UHPC structure, and the dynamic deflection of the UHPC pavement structure increases exponentially with increasing fatigue load. The fatigue life is about 1.2 × 10⁷ cycles under a fixed force of 9 kN and a dynamic deflection of 0.35 mm, which meets the requirements for fatigue performance of pavements on steel bridge decks under traffic conditions of large flow and heavy load.

关键词： steel bridge deck pavement ultra-high-performance concrete epoxy resin composite structure bending fatigue performance

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Cutting performance of surgical electrodes by constructing bionic microstriped structures

《机械工程前沿（英文）》 2023年第18卷第1期 doi: 10.1007/s11465-022-0728-9

摘要： Surgical electrodes rely on thermal effect of high-frequency current and are a widely used medical tool for cutting and coagulating biological tissue. However, tissue adhesion on the electrode surface and thermal injury to adjacent tissue are serious problems in surgery that can affect cutting performance. A bionic microstriped structure mimicking a banana leaf was constructed on the electrode via nanosecond laser surface texturing, followed by silanization treatment, to enhance lyophobicity. The effect of initial, simple grid-textured, and bionic electrodes with different wettabilities on tissue adhesion and thermal injury were investigated using horizontal and vertical cutting modes. Results showed that the bionic electrode with high lyophobicity can effectively reduce tissue adhesion mass and thermal injury depth/area compared with the initial electrode. The formation mechanism of adhered tissue was discussed in terms of morphological features, and the potential mechanism for antiadhesion and heat dissipation of the bionic electrode was revealed. Furthermore, we evaluated the influence of groove depth on tissue adhesion and thermal injury and then verified the antiadhesion stability of the bionic electrode. This study demonstrates a promising approach for improving the cutting performance of surgical electrodes.

关键词： surgical electrodes tissue adhesion thermal injury bionic structures cutting performance medical tools

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Recovery and reuse of floc sludge for high-performance capacitors

《环境科学与工程前沿（英文）》 2022年第16卷第6期 doi: 10.1007/s11783-021-1512-5

摘要：

• The feasibility of facile fabrication of capacitor from floc sludge is discussed.

关键词： Floc sludge Porous carbon electrode Energy storage performance Supercapacitors

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Discrete-event stochastic systems with correlated inputs: Modeling and performance evaluation

《工程管理前沿（英文）》 2022年第9卷第2期页码 214-220 doi: 10.1007/s42524-022-0192-6

摘要： In the majority of the previous works on discrete-event stochastic systems, they have been assumed to have independent input processes. However, in many applications, these input processes can be highly correlated. Furthermore, the performance measures of the systems with correlated inputs can be significantly different from those with independent inputs. In this paper, we provide an overview on some commonly used methods for modeling correlated input processes, and we discuss the difficulties and possible future research topics in the study of discrete-event stochastic systems with correlated inputs.

关键词： discrete-event stochastic system correlated input performance evaluation

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Weakening behavior of waterproof performance in joints of shield tunnels under adjacent constructions

《结构与土木工程前沿（英文）》页码 884-900 doi: 10.1007/s11709-022-0912-3

摘要： Groundwater leakage in shield tunnels poses a threat to the safety and durability of tunnel structures. Disturbance of adjacent constructions during the operation of shield tunnels frequently occurs in China, leading to deformation of tunnel lining and leakage in joints. Understanding the impact of adjacent constructions on the waterproofing performance of the lining is critical for the protection of shield tunnels. In this study, the weakening behavior of waterproof performance was investigated in the joints of shield tunnels under transverse deformation induced by adjacent construction. First, the relationship between the joint opening and transverse deformation under three typical adjacent constructions (upper loading, upper excavation, and side excavation) was investigated via elaborate numerical simulations. Subsequently, the evolution of the waterproof performance of a common gasket with a joint opening was examined by establishing a coupled Eulerian–Lagrangian model of joint seepage, and a formula describing the relationship between waterproof performance and joint opening was proposed. Finally, the weakening law of waterproofing performance was investigated based on the results of the aforementioned studies. It was determined that the joints with the greatest decline in waterproof performance were located at the tunnel shoulder in the upper loading case, tunnel crown in the upper excavation case, and tunnel shoulder in the side excavation case. When the waterproof performance of these joints decreased to 50% and 30%, the transverse deformations were 60 and 90 mm under upper loading, 90 and 140 mm under upper excavation, and 45 and 70 mm under side excavation, respectively. The results provide a straightforward reference for setting a controlled deformation standard considering the waterproof performance.

关键词： shield tunnel waterproof performance horizontal transverse deformation joint opening weakening behavior

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Facility managers’ perceptions on building performance assessment

Rafaela BORTOLINI, Núria FORCADA

《工程管理前沿（英文）》 2018年第5卷第3期页码 324-333 doi: 10.15302/J-FEM-2018010

摘要：

During the operational phase, building performance may decrease in various areas, so that the end users’ requirements are no longer met. Consequently, indicators are useful to assess and improve the performance of existing buildings. In this study, we carried out a literature review and organized a focus group with facility management experts to gather and analyze facility managers’ perceptions on operational indicators that could be used to assess the performance of buildings. The results revealed that the core indicators used to measure a building’s operational performance are related to safety and assets working properly, health and comfort, space functionality, and energy performance. The findings also revealed that these indicators can be obtained from three sources: a) facility managers/operators, who carry out corrective maintenance and perform technical inspections, b) regular users, who report complaints and fill-in satisfaction questionnaires, and c) sporadic users, who also fill-in satisfaction questionnaires. These indicators and their sources can contribute to a better analysis of building performance and the definition of measures to improve performance during the operational phase of a building.

关键词： building performance facility management non-residential buildings

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Nonlinear design-point performance adaptation approaches and their comparisons for gas turbine applications

Y. G. LI, P. PILIDIS,

《能源前沿（英文）》 2009年第3卷第4期页码 446-455 doi: 10.1007/s11708-009-0042-9

摘要： Accurate performance simulation and understanding of gas turbine engines is very useful for gas turbine manufacturers and users alike and such a simulation normally starts from its design point. When some of the engine component parameters for an existing engine are not available, they must be estimated in order that the performance analysis can be started. Therefore, the simulated design point performance of an engine may be slightly different from its actual performance. In this paper, two nonlinear gas turbine design-point performance adaptation approaches have been presented to best estimate the unknown component parameters and match available design point engine performance, one using a nonlinear matrix inverse adaptation method and the other using a Genetic Algorithm-based adaptation approach. The advantages and disadvantages of the two adaptation methods have been compared with each other. In the approaches, the component parameters may be compressor pressure ratios and efficiencies, turbine entry temperature, turbine efficiencies, engine mass flow rate, cooling flows, and by-pass ratio, etc. The engine performance parameters may be thrust and SFC for aero engines, shaft power, and thermal efficiency for industrial engines, gas path pressures, temperatures, etc. To select the most appropriate to-be-adapted component parameters, a sensitivity bar chart is used to analyze the sensitivity of all potential component parameters against the engine performance parameters. The two adaptation approaches have been applied to a model gas turbine engine. The application shows that the sensitivity bar chart is very useful in the selection of the to-be-adapted component parameters, and both adaptation approaches are able to produce good quality engine models at design point. The comparison of the two adaptation methods shows that the nonlinear matrix inverse method is faster and more accurate, while the genetic algorithm-based adaptation method is more robust but slower. Theoretically, both adaptation methods can be extended to other gas turbine engine performance modelling applications.

关键词： gas turbine engine performance adaptation performance matching design-point performance simulation influence coefficient matrix genetic algorithm